Technical And Leadership Support. Draft Pfas National Management Plan. Seeing the power of White Island firsthand. Research Check: will using lice products give my children behavioural problems? How a saviour of the ozone hole became a climate change villain — and how we're going to f.. Displaying the most recent project by Ian Rae. Displaying the most recent scholarly works by Ian Rae. In the ozone fervour of the mid-nineteenth century, the ability of ether, turpentine, and other unsaturated oils to take up oxygen.. When the PhD was introduced in England, consideration was also being given to its introduction in Australia.
The University of Mel.. A range of peptide analogues related to Asuhuman growth hormone have been synthesized and tested for hypoglycaemic activ.. Methyl E - and Z methyl 3-D propenoates were prepared from E bromomethylpro- penoic acid. Polymerization by free r.. Two isomeric pairs of 3-bromopropenoic acids were prepared and vicinal C-H couplings were measured in their 13C n.
Some guanidines, related in structure to mianserin and to 2-methyl-1,2,9,13b-tetrahydro-3H-dibenz[c,f]imadazo[1,5a] azepinim.. The synthesis and incorporation of two different isomeric gamma-lactam structures into peptide analogues related to hGH  are.. Relaxation times T1 and methyl-methyl nuclear Overhauser effects were measured for 1H, 13C and 2H nuclei in 1,2,2,6,6-pentameth.. A range of compounds with methyl groups disposed ortho and peri on heteroaromatic frameworks have been prepared, and T1 values.. Thermal degradation of a model for the 'unsaturated end group' of poly methyl methacrylate gives products which suggest that ho..
As a model for a poly methyl methacrylate chain which contains a head-to-head unit, the thermal degradation of tetramethyl 2,4,.. Hydrogen relaxation in the papaverine molecule in CDCl3 solution has been studied so as to derive the conformation about the C In order to obtain a deeper insight into the title effect, several compounds with an F atom very close to a C-H of a nearby functi.. The regioselectivity of reaction of tricarbonyl 1,1- dimethylindane chromium with selected electrophiles and nucleophiles.. Three series of selectively deuterated toluenes, 2-chlorotoluenes and 2,6-dichlorotoluenes have been synthesized, and their methyl..
A random copolymer of methyl methacrylate and its D5 analogue has been used to show that thermal degradation of the polymer reg.. Reversed-phase high-performance liquid chromatography was used for both analytical and preparative separations of several steroida..
The 4J fluorine-fluorine coupling over four bonds involving an sp3 carbon and two sp2 carbons has been studied by using constraine.. A number of new arenetricarbonylchromium compounds have been synthesized in which the arene ring is substituted with a number of l..
Spin-spin coupling between an aromatic fluorine and fluorines in an adjacent side chain Ar-C-C-F , with J values in the range An attempt to modify the previously reported synthesis of the tricyclic system 1 of mycorrhizin A 2 and gilmicolin 3 by very..
Conformational analyses by 1H NMR and potential-energy calculations are reported for the ergot alkaloids ergotamine and ergotamini.. The cyclopropa[c]benzofuran derivative 17 , which contains the structural features of methyl ethers of mycorrhizin A and gilmicol.. In 3- phenylmethyl piperazine-2,5-dione cyclo Phe-Gly the C6 methylene hydrogens are shielded by the aromatic ring which lies a..
Reaction of piperazine-2,5-dione with 2-formylbenzoic acid in the presence of triethylamine gives three products: 1- 3'-oxo-1',3' The 13C n.
The crystal structure of N-acetylpiperidinecarboxylic acid has been determined by single-crystal X-ray diffraction methods at A number of substituted 1,4-difluorobenzenes were examined by 19F n. In 4,6-disubstituted N,N'- 1,3-phenylene bispivalamides, the ring hydrogen between the two amide groups is deshielded by both and.. The 13C and 1H N. The reactions of C-benzoylnitrones with allylamine afford tetrahydro-5H-pyrrolo[3,4-c]isoxazoles resulting from imine formation an.. Attempts to generate the 1-methylphenylbicyclo[2,2,1]heptyl cation 6 by reaction of 1-methyl-exophenylbicyclo[2,2,1]hep..
The constitution of a number of 2- iminomethyl benzenethiols and 2- iminomethyl nitrobenzene-thiols has been studied by 1H N. Reaction of 1,8-cineole with hydrogen over supported platinum and palladium catalysts gives mixtures of cis- and trans-p-menthanes.. Fluorine-fluorine coupling over four bonds has been observed in the 19F N. The 13C chemical shifts of some triphenyl-phosphine and -arsine dicarbonyl arene chromiums are reported.
The shifts are discussed.. The effects of lanthanide shift reagents on the spectra of thioamides and related amides and selenoamides are reported, and compar.. A rational synth.. Several cyclohexanones have been converted, via cyclohexylidenebutyric acids, into 3,4,5,6,7,8-hexa-hydronaphthalen-1 2H -ones in..
The spectra are interpreted in terms of el.. For 4? Cineolic anhydride is attacked by nucleophiles exclusively at its more exposed carbonyl group.
The dimethyl ester of cineolic acid.. Anisotropic deshielding b.. Furfuraldehyde, 4-hydroxybenzaldehyde, and 4-hydroxymethoxybenzalde- hyde were converted into 2-furylacetic, 4-hydroxyphenylace..
The reaction of o-dinitrobenzene with sodium borohydride in aqueous dimethyl sulphoxide at room temperature gives nitrobenzene and.. A series of 2-substituted 3,5-dimethylanilines and their N-acetyl derivatives have been synthesized, and their proton magnetic res.. The co.. When one of a pair of substituents ortho to each other on a benzene ring is conjugated with an appropriate para substituent, it is..
A number of 2-substituted 1,3-phenylenediamines and their N-acyl and N,N? The proton magnetic resonance spectra of deuterochloroform solutions of a number of ortho-substituted anilines and their S-acyl de.. The differences between proton mangetic resonance spectra of aromatic nitro compounds in deuterochloroform and dimethyl sulphoxide.. Proton magnetic resonance spectroscopy has been used to examine the conformations of a number of ortho-nitroanilines in solution. Proton-proton spin-spin coupling in the system H-C-N-H has been observed in a series of N-methylanilines.
The proton magnetic resonance chemical shifts of N-methyl protons in para-substituted NN-dimethylanilines have been correlated wit.. The product of methylation of 4-benzamido-1,2-dithiolethione has been shown to be methyl 5-methylthiophenyloxazolecarbodi.. The chemical shift of an aromatic proton adjacent to a nitro group is sensitive to the degree of coplanarity between the nitro gro..
A new examination of the heartwood of Pterocarpus indicus has revealed the presence of formononetin, isoliquiritigenin, - -p-hydr.. Displaying the 4 most recent news articles by Ian Rae. Prof Ian Rae Honorary Chemistry. Prof Ian Rae. Enquiries Contact Ian. Division Science. Enquiries Contact. Find out more about Ian Rae's experience.
Ian Rae's highlights. James Douglas Morrison Journal article. Editors' Page Journal article. Projects Displaying the most recent project by Ian Rae. Project Types. Scholarly Works Displaying the most recent scholarly works by Ian Rae.
James Douglas Morrison Editors' Page. John Melvin Swan Ideal gases: anaesthetics in the heart of the twentieth century. Elemental micro-analysis of organic compounds. The Australian experience. Direct detection of brominated flame retardants from plastic e-waste using liquid extraction surface analysis mass spectrometry.
Indigo Dreaming. Athelstan Laurence Johnson Beckwith Marine Pharmacology in Australia. Banned Solvents. Managing the intractable: Communicative structures for management of hexachlorobenzene and other scheduled wastes. Geoffrey Malcolm Badger Geoffrey Malcolm Badger — Chemistry Melbourne High tech trash: Digital devices, hidden toxics, and human health. Something in the air: connections between global warming, ozone depletion, POPs and particulates. Appointing a professor: Reflections on filling the chair of organic chemistry at the University of Sydney in